Latest Projects

3D Printed Micro-Pyramids for Cells

“Programming Mechanics and Physicochemical Properties of 3D Hydrogel Cellular Microcultures via Direct Ink Writing,” McCracken, J. M.; Badea, A.; Kandel, M. E.; Gladman, A. S.; Wetzel, D. J.; Popescu, G.; Lewis, J. A.; Nuzzo, R. G. Advanced Healthcare Materials 2016, 5,1025–1039 DOI: 10.1002/adhm.201500888.

For more information about recent work within the soft materials cluster:

Luminescent Solar Concentrators

“Enhanced Photon Collection in Luminescent Solar Concentrators with Distributed Bragg Reflectors,” Xu, L.; Yao, Y.; Bronstein, N. D.; Li; L.; Alivisatos, A. P.; Nuzzo, R. G. ACS Photonics 2016, 2, ASAP DOI: 10.1021/acsphotonics.5b00630.

For more information about recent work within the solar cluster:

Magnesium Anode Passivation Dynamics

“Passivation Dynamics in the Anisotropic Electrochemical Deposition and Stripping of Bulk Magnesium Metal Anodes,” Wetzel, D. J.; Malone, M. Jr.; Zavadil, K. R.; Gewirth A. A.; Nuzzo, R. G. ACS Applied Materials and Interfaces, 2015, 7, 18406−18414DOI:10.1021/acsami.5b04487.

For more information about recent work within the electrochemistry cluster:


[299] “Enhanced Emission of Quantum Dots Embedded Within the High-Index Dielectric Regions of Photonic Crystal Slabs,” See, G. G.; Naughton, M.S.; Xu, L.; Nuzzo, R. G.; Kenis, P. J. A.; Cunningham, B. T. AppliedPhysics Letters 2016,108, 171108/1-4 DOI: 10.1063/1.4948379.

[298]“Programming Mechanics and Physicochemical Properties of 3D Hydrogel Cellular Microcultures via Direct Ink Writing,” McCracken, J.M.; Badea, A.; Kandel, M. E.; Gladman, A. S.; Wetzel, D. J.; Popescu,G.; Lewis, J. A.; Nuzzo, R. G. Advanced Healthcare Materials 2016,5,1025–1039 DOI: 10.1002/adhm.201500888.

[297]“Enhanced Photon Collection in Luminescent Solar Concentratorswith Distributed Bragg Reflectors,” Xu, L.; Yao, Y.; Bronstein, N. D.;Li; L.; Alivisatos, A. P.; Nuzzo, R. G. ACS Photonics 2016, 2, ASAPDOI: 10.1021/acsphotonics.5b00630.

[296]“Biomimetic 4D Printing,” Gladman, A. S.; Matsumoto, E. A.;Nuzzo, R. G.; Mahadevan, L.; Lewis, J. A. Nature Materials 2016, 15,413–418 DOI:10.1038/nmat4544.

[295]“Design, Fabrication, and Characterization of a Microchannel Water Electrolyzer,” Oruc, M. E.; Desai, A. V.; Kenis, P. J. A.; Nuzzo,R. G. Journal of Power Sources 2016,307, 122-128 DOI:10.1016/j.jpowsour.2015.12.062.

[294]“3D Scaffolded Nickel–Tin Li-Ion Anodes with Enhanced Cyclability,” Zhang, H.; Shi, T.; Wetzel, D. J.; Nuzzo, R. G.; Braun,P. V Advanced Materials 2016, 28,742–747 DOI: 10.1002/adma.201504780

[293] “Full Solar Spectrum Conversion via Multi-junction Architectures and Optical Concentration,” Yao, Y.; Xu, L.; Sheng, X.; Bronstein, N.D.; Rogers, J. A.; Alivisatos, A. P.; Nuzzo, R. G. Journal of Optics, 2016, 18,073004/24-25 DOI:10.1088/2040-8978/18/7/073004.

[292] “Comprehensive Energy Analysisof a Photovoltaic Thermal Water Electrolyzer,” Oruc, M. E.; Desai, A. V.; Kenis, P. J. A.; Nuzzo, R. G.Applied Energy 2016,164, 294-302 DOI: 10.1016/j.apenergy.2015.11.078.


[291] “Improving Electrodeposition of Mg through an Open Circuit Potential Hold,” Esbenshade, J. L.; Barile, C. J.; Fister, T. T.;Bassett, K. L.; Fenter, P.; Nuzzo, R. G.; Gewirth, A. A. J. Phys. Chem.C 2015,119, 23366–23372 DOI: 10.1021/acs.jpcc.5b07825

[290] “Intracluster Atomic andElectronic Structural Heterogeneities ofSupported Nanoscale Metal Catalysts,” Elsen, A.; Jung, U.; Vila, F.;Li, Y.; Safonova, O.; Thomas, R.; Tromp, M.; Rehr, J. J.; Nuzzo, R. G.;Frenkel, A. I. J. Phys.Chem. C 2015,119, 25615–25627 DOI:10.1021/acs.jpcc.5b08267.

[289] “Oxygen Reduction Reaction Induced pH-Responsive Chemo-Mechanical Hydrogel Actuators,” Yuan, P.; Yu, C.; Erickson, E. M.; Daly, C. M.;Rogers, J. A.; Nuzzo, R. G. SoftMatter, 2015,11, 7953-7959 DOI:10.1039/C5SM01892G.

[288] “Nanomembranes and Soft Fabrication Methods for High Performance,Low Cost Energy Technologies,” Yao, Y.; Nuzzo, R. G. Proceedings of theSPIE, 2015,9608, 960818/1-7 DOI: 10.1117/12.2185516.

[287] “Operando Characterization of Catalysts through use of a Portable Microreactor,“ Zhao, S.; Li, Y.; Stavitski, E.; Tappero, R.; Crowley,S.; Castaldi, M. J.; Zakharov, D. N.; Nuzzo, R. G.; Frenkel, A. I.;Stach, E. A. ChemCatChem,2015, 7,3683–3691 DOI:10.1002/cctc.201500688.

[286] “Passivation Dynamics in the Anisotropic Electrochemical Deposition and Stripping of Bulk Magnesium Metal Anodes,” Wetzel, D.; Malone, M.Jr.; J.; Zavadil, K. R.; Gewirth A. A.; Nuzzo, R. G. ACS Applied Materials and Interfaces, 2015, 7, 18406−18414DOI:10.1021/acsami.5b04487.

[285] “Polarized Quantum Dot Emission in Electrohydrodynamic JetPrinted Photonic Crystals,” See, G. G.; Xu, L.; Sutanto, E.; AlleyneA.; Nuzzo, R. G.; Cunningham, B. T. Applied Physics Letters,2015, 107,051101/1-4 DOI: 10.1063/1.4927648.

[284] “Quantum Dot Luminescent Concentrator Cavity Exhibiting 30-fold Concentration,” Bronstein, N. D.; Yao, Y.; Xu, L.; O’Brien, E.; Powers,A. S.; Ferry, V. E.; Alivisatos, A. P.; Nuzzo, R. G. ACS Photonics,2015, 2,1576–1583 DOI: 10.1021/acsphotonics.5b00334.

[283] "Exploring Salt and SolventEffects in Chloride-Based Electrolytes for Magnesium Electrodeposition and Dissolution," Barile,C.; Nuzzo, R. G.; Gewirth, A. A. J.Phys. Chem. C 2015,119,13524–13534 DOI: 10.1021/acs.jpcc.5b03508.

[282] “Complex Structural Dynamics of Nanocatalysts Revealed inOperando Conditions by Correlated Imaging and Spectroscopy Probes,” Li,Y.; Zakharov, D.; Zhao, S.; Tappero, R.; Jung, U.; Elsen, A.; Baumann,P.; Nuzzo, R. G.; Stach E. A.; Frenkel A. I. Nature Communications2015DOI: 10.1038/ncomms8583.

[281] “Programming Soft Matter via Strain,” Motala, M. J.; Hsia, K. J.;Nuzzo, R. G. Extreme Mechanics Letters 2015,3, 8-15DOI:10.1016/j.eml.2015.04.004.

[280] “Region Specific Enhancement of Quantum Dot Emission using Asymmetric Two-Dimensional Photonic Crystals,” See, G. G.; Xu, L.; Naughton, M. S.; Tang, T.; Bonita, Y.; Kenis, P. J. A.; Nuzzo, R. G.;Cunningham, B. T. AppliedOptics 2015,54, 2302-2308 DOI:10.1364/AO.54.002302.

[279] “Synergetic Role of Li+ during Mg Electrodeposition/Dissolutionin Borohydride Diglyme Electrolyte Solution: Voltammetric Stripping Behaviors on a Pt Microelectrode Indicative of Mg-Li Alloying and Facilitated Dissolution,” Chang, J.; Haasch, R. T.; Spila, T. P.; Kim,J.; Braun, P. V.; Gewirth, A. A.; Nuzzo, R. G. ACS Applied Materialsand Interfaces 2015,7, 2494–2502 DOI: 10.1021/am507375t.

[278] “Comparative In-Operando Studies in Heterogeneous Catalysis: Atomic and Electronic Structural Features in the Hydrogenation of Ethylene over Supported Pd and Pt Catalysts (Perspective),” Jung, U.;Elsen, A.; Li, Y.; Smith, J. G.; Small, M. W.; Stach, E. A.; Frenkel,A. I.; Nuzzo, R. G. ACSCatalysis 2015,5, 1539–1551DOI:10.1021/cs501846g.

[277] “Deterministic Assembly of Functional Micro/Nanomaterials Into Complex, Three-Dimensional Architectures by Compressive Buckling,” Xu,S.; Yan, Z.; Jang, K.; Huang, W.; Fu, H.; Kim, J.; Flavin, M.; Wei, Z.;Wang, R.; McCracken, J.; Liu, H.; Xiao, D.; Zhou, G.; Chung, H. U.;Cheng, H.; Badea, A.; Ren, W.; Banks, A.; Li, X.; Paik, U.; Nuzzo, R.G.; Huang, Y.; Zhang, Y.; Rogers, J. A. Science 2015, 347, 154-159DOI:10.1126/science.1260960.

[276]“Electrolytic Conditioning of a Magnesium Aluminum Chloride Complex for Reversible Magnesium Deposition,” Barile, C. J.; Miller, E.C.; Zavadil, K. R.; Nuzzo, R. G.; Gewirth, A. A. J. Phys. Chem. C.2014, 118,27623–27630 DOI: 10.1021/jp506951b.

[275] “Inorganic Materials and Assembly Techniques for Flexible and Stretchable Electronics,” He, J.; Nuzzo, R. G.; Rogers, J. A.Proceedings of the IEEE2015, 103,619 – 632 DOI:10.1109/JPROC.2015.2396991.

[274] “Influence of Oxides on Stress Evolution and Reversibility during SnOx Conversion and Li-Sn Alloying Reactions,” Tavassol, H.; Cason, M.W.; Nuzzo, R. G.; Gewirth, A. A. Advanced Energy Materials 2015,5,1400317/1-10 DOI: 10.1002/aenm.201400317.


[273]“Black Silicon Solar Thin-Film Microcells Integrating Top Nanocone Structures for Broadband and Omnidirectional Light-Trapping,” Xu, Z.; Yau, Y.; Brueckner, E.; Li,L.; Jiang, J.; Nuzzo, R. G.; Liu, G. L. Nanotechnology2014, 25,305301/1-8 DOI: 10.1088/0957-4484/25/30/305301.

[272]“Microcantilever Stress and In-situEXAFS Observations of Platinum Bond Expansion Due to Oxygen Adsorption during the Oxygen Reduction Reaction,”Erickson, E. M.; Wetzel, D.; Oruc, M. E.; Cason, M. W.; Hoang, T.;Small, M.W.; Diya, L.; Frenkel, A. I.; Gewirth, A. A.; Nuzzo, R. G. Analyt. Chem. 2014,86, 8368–8375 DOI:10.1021/ac5019149.

[271]“Printing-Based Assembly of Quadruple Junction, Four-Terminal Microscale Solar Cells and Their Use in High-Efficiency Modules” Sheng, X.; Bower, C.A.; Bonafede, S.; Wilson, J. W.; Fisher, B.; Meitl, M.; Yuen, H.; Wang,S.;Shen,L.; Banks, A. R.; Corcoran, C. J.; Nuzzo, R. G.; Burroughs, S.;Rogers,J. A. Nature Materials 2014, 13, 593-598 DOI:10.1038/nmat3946.

[270] “Effects of Adsorbate Coverage and Bond Length Disorder on thed-Band Center in Carbon-Supported Pt Catalysts,” Small, M. W.; Kas, J.;Kvashnina, K.O.; Rehr, J. J.; Nuzzo, R. G.; Tromp, M.; Frenkel, A. I. Chem.Phys.Chem. 2014,onlineview DOI: 10.1002/cphc.201400055.[269]"Luminescent Solar Concentration with Semiconductor Nanorods and Transfer-Printed Micro-Silicon Solar Cells," Bronstein, N.; Li, L. ; Yao, Y. ; Xu, L.;Alivisatos, A.P.; Nuzzo, R. G. ACS Nano. 2014, 8,44–53 DOI: 10.1021/nn404418h

[268]“Enhanced Ultraviolet Responses in Thin-film InGaP Solar Cells by Down-Conversion,” Sheng, X.; Corcoran,C. J.; He, J.; Shen, L.; Kim, S.; Park, J.; Nuzzo, R. G.; Rogers, J. A.Phys. Chem. Chem. Phys. 2013, 15,20434-20437 DOI: 10.1039/c3cp54096k.

[267]“A Finite-Deformation Mechanics Theory for Kinetically Controlled Transfer Printing,” Feng, X.; Cheng, H.; Bowen, A. M.; Carlson, A. W.;Nuzzo, R.G.;Rogers, J. A.  Journal ofApplied Mechanics 2013, 80, 061023-061023-5 DOI:10.1115/1.4023963.

[266]“Critical Review: Effects of Complex Interactions on Structure and Dynamics of Supported Metal Catalysts,” Frenkel, A. I.; Cason, M. W.;Elsen, A.;Jung, U.; Small, M. W.; Nuzzo, R. G.; Vila, D. V.; Rehr, J. J.; Stach,E. A.;Yang, J. C. J. Vac. Sci. Technol. A 2014, 32,020801/1-17 DOI: 10.1116/1.4820493.


[265]“Fabrication and Assembly of Ultra-thin Monocrystalline Silicon SolarMicrocells Integrating Electrical Passivation and Anti-reflectionCoatings,”Yao, Y.; Brueckner, E.; Li, L.; Nuzzo, R. G. Energy&Environmental Science 2013,6,3071-3079 DOI10.1039/c3ee42230e.

[264]“Model Ge Microstructures as Anodes for Li-ion Batteries,” Long, B. R.;Goldman, J. L.; Nuzzo, R. G.; Gewirth, A. A.  Journalof Solid StateElectrochemistry 2013, 17,3015-3020 DOI:10.1007/s10008-013-2148-6.

[263]“Amorphous to Crystalline Transformations in Nanoparticles," Li, L.;Wang,L.-L.; Johnson, D. D.; Zhang, Z.; Sanchez, S. I.; Kang, J. H.; Nuzzo,R. G.;Wang, Q.; Frenkel, A. I.; Li, J.; Ciston, J.; Stach, E. A.; Yang, J. C.J. Am. Chem. Soc. 2013,135,13062–13072 DOI:10.1021/ja405497p.

[262]“Directed Transport as a Route to Improved Performance inMicropore-modifiedEncapsulated Multilayer Silicon Electrodes,” Goldman, J. L.; Cason, M.W.;Wetzel, D. J.; Vicker, H.; Beyer, A.; Gölzhäuser, A.; Nuzzo, R. G.;Gewirth A.A. J. Electrochem. Soc. 2013, 160,A1746-A1752 DOI: 10.1149/2.047310jes.

[261]"Quantitative Reflection Imaging of Fixed AplysiaCalifornica PedalGanglion Neurons on Nanostructured Plasmonic Crystals" Le, A.-P.; Kang,S.; Thompson, L. B.; Rubakhin, S. S.; Sweedler, J. V.; Rogers, J. A.;Nuzzo, R.G. J. Phys. Chem. B. 2013,ASAP DOI:10.1021/jp402731f.

[260]“AnIn­-situ Study of Bond Strains in 1nm Pt Catalysts and theirSensitivities to Cluster-Support and Cluster-Adsorbate Interactions,”Frenkel,A. I.; Small, M. W.; Smith, J. G.; Nuzzo, R. G.; Kvashnina, K. O.;Tromp, M. J. Phys. Chem. C 2013,117,23286–23294 DOI:10.1021/jp4062658.

[259]“Light Trapping in Ultra-thin Monocrystalline Silicon Solar Cells,” Yu,K. J.;Park, J. S.; Lee, Y. R.; Corcoran, C.; Nuzzo, R. G.; Chanda, D.;Rogers, J. A. Advanced Energy Materials 2013, 3,1401–1406 DOI: 10.1002/aenm.201300542.

[258]“Doubling the Power Output of Bifacial Thin-Film GaAs Solar Cells withLuminescentConcentration,” Sheng, X.; Shen, L.; Kim, T.; Li, L.; Dowdy, R.;Froeter, P.;Wang, X.; Shigeta, K.; Li, X.; Nuzzo, R. G.; Giebink, N. C.; Rogers, J.A. Advanced Energy Materials 2013, 3,991-996 DOI: 10.1002/aenm.201201064.

[257]“Electronically Programmable, Reversible Shape Change in Two- andThree-Dimensional Hydrogel Structures,” Yu, C.; Duan, Z.; Yuan, P.; Li,Y.; Su,Y.; Zhang, X.; Pan, Y.; Dai, L. L.; Nuzzo, R. G.; Huang, Y.; Jiang, H.;Rogers,J. A. Advanced Materials 2013, 25,1541-1546 DOI: 10.1002/adma.201204180.

[256]“Short Range Order in Bimetallic Nanoalloys: an Extended X-RayAbsorption FineStructure Study,” Frenkel, A. I.; Wang, Q.; Sanchez, S. I.; Small, M.W.;Nuzzo, R. G. J. Chem. Phys. 2013, 138,064202/1-7 DOI: 10.1063/1.4790509.

[255]“X-Ray Diffraction Microscopy of Lithiated Silicon Microstructures,”Fister, T.T.; Goldman, J. L.; Long, B. R.; Nuzzo, R. G.;Gewirth, A.A.;Fenter, P. A. J. Appl. Phys. 2013, 102,131903/1-4 DOI: 10.1063/1.4798554.

[254]“Metastability and Structural Polymorphism in Noble Metals (Au, Ag, Pt,Pd, Irand Rh): the Role of Composition and Metal Atom Coordination in Mono-andBimetallic Nanoclusters,” Sanchez, S. I.; Small, M. W.; Bozin, E. S.;Wen,J.-G.; Zuo, J.-M.;. Nuzzo, R. G. ACS Nano 2013, 7,1542-1547 DOI:10.1021/nn305314m.

[253]“Ultrathin Silicon Solar Micro-Cells with an Integrated NanostructuredBacksideReflector for Enhanced Optical Absorption,” Corcoran, C. J.; Kang, S.;Chanda,D.; Li, L.; Guo, X.; Chanda, D.; Nuzzo, R. G. ACSAppliedMaterials and Interfaces 2013,5,4239-4246 DOI:10.1021/am400408g.

[252]“UV Patternable Thin Film Chemistry for Shape and FunctionallyVersatileSelf-Oscillating Gels,” Yuan. P.; Kuksenok, O.; Gross, D. E.; Balazs,A. C.;Moore, J. S.; Nuzzo, R. G. Soft Matter2013, 9,1231-1243 DOI:10.1039/c2sm27100a.

[251]“A Finite-Deformation Mechanics Theory for Kinetically ControlledTransferPrinting,” Feng, X.; Bowen, A. M.; Meitl, M. A.; Huang, Y.; Nuzzo, R.G.;Rogers, J. A. J. Appl. Mech. 2013, 80, 061023.


[250]“Functional Protein Microarrays by Electrohydrodynamic Jet Printing,”Shigeta,K.; He, Y.; Sutanto, E.;Kang, S.;Le, A.-P.;Nuzzo, R. G.; Alleyne, A.G.; Ferreira, P.M.;Lu, Y.; Rogers, J. A. Analyt.Chem. 2012. 84, 10012-10018 DOI:10.1021/ac302463p.

[249]“A Thermal Analysis of the Operation of Microscale Inorganic LightEmittingDiodes,” Lu, C.; Li, Y.; Kim, H.-S.; Brueckner, E.; Fang, B.; Hwang,K.; Huang,Y.; Nuzzo, R. G.; Rogers, J. A. Proc.Royal Society A. 2012 468,3215-3223 DOI:10.1098/rspa.2012.0225.

[248]“Transfer Printing Techniques for Materials Assembly andMicro/NanodeviceFabrication,” Carlson, A. W.; Bowen, A. M.; Hong, Y.; Nuzzo, R. G.;Rogers, J.A. Advanced Materials 2012, 24,5284-5318 DOI: 10.1002/adma.201201386.

[247]“The Influence of Adsorbates on the Electronic Structure, Bond Strain,andThermal Properties of Supported, Nanoscale Noble Metal Catalysts,”Small, M.W.; Sanchez, S. I.; Marinkovic, N. S.; Frenkel, A. I.; Nuzzo, R. G. ACS Nano 2012,6,5583-5595 DOI: 10.1021/nn3015322.

[246]“Recent Developments and Applications of Electron Microscopy toHeterogeneousCatalysis,” Yang, J. C.; Small, M. W.; Grieshaber, R. V.; Nuzzo, R. G. Chem. Soc. Rev. 2012,41,8179-8194 DOI:10.1039/c2cs35371g.

[245]“Triangular Elastomeric Stamps for Optical Applications: Near-fieldPhase ShiftPhotolithography, 3-D Proximity Field Patterning, EmbossedAnti-reflectiveCoatings, and SERS Sensing,” Bowen, A. M.; Motala, M. J.; Lucas, J. M.;Gupta,S.; Baca, A. J.; Mihi, A.; Alivisatos, P.; Braun, P. V.; Nuzzo, R. G. Advanced Functional Materials 2012,ASAP, DOI:10.1002/adfm.201102455.

[244]“In-Situ Electrochemical X-rayAbsorption Spectroscopy of OxygenReductionElectrocatalysis with High Oxygen Flux,” Erickson, E. M.; Thorum, M.S.; Vasić,R.; Marinković, N. S.; Frenkel, A. I.; Gewirth, A. A.; Nuzzo, R. G. J. Amer. Chem. Soc. 2012,134,197-200 DOI:10.1021/ja210465x.


[243]“Synthesis, Assembly and Applications of Semiconductor Nanomembranes,”Rogers,J. A.; Lagally, M. G.; Nuzzo, R. G. Nature2011, 477,45-53 DOI:10.1038/nature10381.

[242]“Unusual Strategies for Using Indium Gallium Nitride Grown on Silicon(111) forSolid State Lighting,” Kim, H.-S.; Brueckner, E.; Song, J.; Kim, S.;Li, Y.;Lu, C.; Sulkin, J.; Choquette, K.; Huang, Y.; Nuzzo, R. G.; Rogers,J.A. Proc. Nat. Acad. Sci. 2011, 108,10072-10077 DOI: 10:1073/pnas1102650108.

[241]“Soft Embossing of Nanoscale Optical Structures in Glass,” Yao, J.; Le,A.-P.;Schulmerich, M.; Maria, J.; Lee, T.-W.; Gray, S. K.; Bhargava, R.;Rogers, J.A.; Nuzzo, R. G. ACS Nano, 2011, 5,5763-5774 DOI: 10.1021/nn201464t.

[240]“Flexible Concentrator PhotovoltaicsBased on Microscale Silicon Solar Cells Embedded in LuminescentWaveguides,” Yoon,J.; Li, L.; Semichaivsky, A. V.; Ryu, J. H.; Johnson, H. T.; Nuzzo, R.G.;Rogers, J. A. Nature Communications 2011, 2,1318/1-8 DOI: 10.1038/ncomms1318.

[239]“Programmable Chemical Gradient Patterns by Soft GrayscaleLithography,” Bowen,A. M.; Ritchey, J. A.; Moore, J. S.; Nuzzo, R. G. Small2011, 3350-3362DOI 10.1002/smll.201100920.

[238]“Industrial Ziegler-type Hydrogenation Catalysts Made fromCo(neodecanoate)2or Ni(2-ethylhexanoate)2, and AlEt3:Evidence forNanoclusters and Nanocluster-Based Catalysis,” Alley, William M.;Hamdemir,Isil K.; Wang, Qi; Frenkel, Anatoly I.; Li, Long; Yang, Judith C.;Menard,Laurent D.; Nuzzo, Ralph G.; Özkar, Saim;Johnson,Kimberly; Finke,Richard G. Langmuir 2011,27,6279-6294.

[237]“The Atomic Structural Dynamics ofγ-Al2O3 Supported Ir-PtNanocluster CatalystsPreparedFrom a Bimetallic Molecular Precursor: A Study UsingAberration-CorrectedElectron Microscopy and X-ray Absorption Spectroscopy,”Small,M. W.;Sanchez, S. I.; Menard, L. D.; Kang,J. H.; Frenkel, A. I.; Nuzzo, R. G. J.Am. Chem. Soc. 2011, 133,3582-3591.

[236]“Strain Anisotropies and Self-limiting Capacities in Single-Crystalline3DSilicon Microstructures: Models for High Energy Density Li-ion BatteryAnodes,”Goldman, J.; Long, B. R.; Gewirth, A. A.; Nuzzo, R. G. AdvancedFunctional Materials 2011,21, 2412-2422.

[235]“ConformalPrinting ofElectrically Small Antennas ontoThree-Dimensional Surfaces,” Adams,J.J.; Duoss, E. B.;Malkowski, T.F.; Motala,M. J.; Ahn, B. Y.;Nuzzo,R. G.;Bernhard,J. T.;Lewis,J. A. Advanced Materials 2011, 23,1304-1413.

[234]“Theory for Optimal Design of Waveguiding Light Concentrators inPhotovoltaicMicrocell Arrays,” Semichaivsky, A. V.; Johnson, H. T.; Yoon, J.;Nuzzo, R. G.;Li, L.; Rogers, J. A. Applied Optics, 2011, 50,2799-2808.

[233]“Genotypingby Alkaline DehybridizationUsing Graphically Encoded Particles,“ Zhang,,H.;DeConinck, A.J.; Slimmer, S. C.; Doyle, P. S.; Lewis, J. A.; Nuzzo, R. G.Chemistry—A European Journal 2011,17,2867-2873.

[232]“A Permeation-Based Microfluidic Direct Formic Acid Fuel Cell (DFAFC),”Erickson, E.; Mitrovski, S. M.; Gewirth, A. A.; Nuzzo, R. G. Journal of Electrophoresis, 2011, 32, 947-956.

[231]“3D Microperiodic Hydrogel Scaffolds for Robust Neuronal Cultures,”HansonShepherd, J.N.; Parker, S. T.; Sheppard, R.F.; Lewis, J. A.; Nuzzo, R. G. AdvancedFunctionalMaterials 2011, 21, 46-54.


[230] “Waterproof AlInGaPOptoelectronics on Flexible Tubing, Sutures,Glovesand Other Unusual Substrates, With Application Examples in BiomedicineandRobotics,” Kim, R.-H.; Kim, D.-H.; Xiao, J.; Kim, B. H.; Park, S.-I.;Panilaitis, B.; Ghaffari, R.; Yao, J.; Li, M.; Liu, Z.; Malyarchuk, V.;Kim, D. G.; Le, A.-P.; Nuzzo, R. G.; Kaplan, D. L.; Omenetto, F. G.;Huang, Y.;Zhan Kang, Z.;  Rogers,J. A. Nature Materials 2010¸ 9,929-937.

[229]“Fabrication of Microstructured Silicon (µs-Si) from a Bulk SingleCrystalWafer and its use in the Fabrication of High Performance Thin FilmTransistorson Plastic Substrates,” Lee, K. J.; Ahn, H.; Motala, M. J.; Nuzzo, R.G.;Menard, E.; Rogers, J. A. Journal ofMicromechanics and Microengineering, 2010,20, AN 075018.

[228]“Guiding Neuron Development with PlanarSurface Gradients of Substrate Cues Deposited using MicrofluidicDevices,”Millet, L. J.; Stewart, M. E.; Nuzzo, R.G.; Gillette, M. U. Lab on aChip 2010, 10,1525-1535.

[227]“Microfluidic Contact Printing: A Versatile Printing-based Platform forPatterning Biomolecular Inks on Hydrogel Substrates,” Zhang, H.;Hanson, J.N.; Nuzzo, R. G. Soft Matter 2010, 6,2238-2245.

[226]“Capillary Induced Self-Assembly of Thin Foils into 3D Structures,” Li,H.; Guo,X.; Nuzzo, R. G.; Hsia, K. J. J. Mech.Phys. Sol. 2010, 58, 2033-2042.

[225]“Compact monocrystalline silicon solar modules with high voltageoutputs andmechanically flexible designs,” Baca, A. J.; Yu, K. J.; Xiao, J.; Yoon,J.;Ryu, J. H.; Stevenson, D.; Nuzzo, R. G.; Rockett, A. A.; Huang, Y.;Rogers, J.A. Energy & Environmental Science2010, 3, 208-211.

[224]“Visualizing Materials Chemistry at Atomic Resolution at AtomicResolution,”Sanchez, S. I.; Small, M. W.; Sivaramakrishnan, S.; Zuo, J.-M; Nuzzo,R. G. Analyt. Chem. 2010,82,2599–2607.

[223]“Bifunctional Polyacrylamide-based Polymers for the Specific Binding ofHexahistidine Tagged Proteins on Au Surfaces,” Thompson, L. B.; Mack,N. H.;Nuzzo, R. G. Phys. Chem. Chem. Phys. 2010, 12,4301-4308.

[222]“Characterization of Ziegler-type Hydrogenation Catalysts Made From[1,5-COD)Ir(µ-O2C8H15)]2and AlEt3or Al(t-Bu)3,” Kayiran, I.;Allet, W. M.; Wang, Q.; Frenkel, A. I.; Menard, L. D.; Nuzzo, R. G.;Ozkar, S.;Johnson, K.; Finke, R. G. Inorg. Chem. 2010, 49,8131-8147.

[221]“Functional Nanostructured PlasmonicMaterials,” Yao,J.; Le,A.-P.; Gray, S. K.; Moore,J. S.; Rogers, J. A.; Nuzzo, R.G. Advanced Materials 2010,22,1102-1110.

[220]“ConjugatedCarbon Monolayer Membranes: Methods for Synthesis and Integration,”Unarunotai, S.; Murata, Y.; Chialvo, C. E.; Mason, N.; Petrov, I.;Nuzzo, R.G.; Moore, J. S.; Rogers, J. A. Advanced Materials 2010, 22, 1072-1077.


style="position:absolute; top: 45%; left: 0pt;"[219]“Nanopost Plasmonic Crystals,” Truong, T. T.; Maria, J.; Yao, J.;Stewart, M.E.; Nuzzo, R. G.; Lee, T.-W.; Gray, S. K.; Rogers, J. A. Nanotechnology2009, 20,434011/1-8.

[218]“Two and Three Dimensional Folding of Thin Film Single-CrystallineSilicon forPhotovoltaic Power Applications,” Guo, X.; Li, H.; Ahn, B. Y.; Duoss,E. B.;Hsia, J.; Lewis, J. A.; Nuzzo, R. G. Proc.Nat. Acad. Sci. 2009, 106,20149-20154.

[217]“Fabrication of Flexible Binary Amplitude Masks for Patterning onHighly CurvedSurfaces,” Bowen, A. M.; Nuzzo, R. G. Adv.Funct. Mater. 2009, 19, 3243-3253.

[216]“Molded Plasmonic Crystals for Detecting and Spatially Imaging SurfaceBoundSpecies by Surface-Enhanced Raman Scattering,” Baca, A. J.; Truong, T.T.;Cambrea, J. R.; Montgomery, J. M.; Abdula, D.; Banks, T. R.; Yao, J.;Nuzzo, R.G.; Gray, S. K.; Rogers, J. A. Appl.Phys. Lett. 2009, 94, 243109/1-3.

[215]“Structural Characterization of Pt-Pd and Pd-Pt Core-Shell NanoclustersatAtomic Resolution,” Sanchez, S. I.; Small, M. W.; Zuo, J.-M; Nuzzo, R.G. J. Amer. Chem. Soc. 2009, 131,8683-8689.

[214]“Optimization of 3D Plasmonic Crystal Structures for QuantitativeRefractiveIndex Sensing,” Maria, J.; Truong, T. T.; Yao, J.; Lee, T.-W.; Nuzzo,R. G.;Leyffer, Sven; Gray, S. K.; Rogers, J. A. J.Phys. Chem. C. 2009, 113,10493-10499.

[213]“Multispectral Thin Film Biosensing and Quantitative Imaging at VisibleWavelengths Using 3D Plasmonic Crystals” Yao, J.; Stewart, M. E.;Maria, J.;Gray, S. K.; Rogers, J. A.; Nuzzo, R. G. Analyt.Chem. 2009, 81,5980-5989.

[212]“Direct-WriteAssembly of 3D Hydrogel Scaffoldsfor Guided Cell Interactions,” Barry, R. A.; Sheppard, R. F.; Hanson,J. N.;Nuzzo, R. G.; Wiltzius, P.; Lewis, J. A. AdvancedMaterials 2009, 21, 2407-2410.

[211]“OmnidirectionalPrinting ofFlexible, Stretchable, and Spanning Silver Microelectrodes,” Ahn, B.Y.; Duoss,E. B.; Motala, M. J.;Guo, X.; Park, S.-I.; Xiong, Y; Yoon, J.; Nuzzo,R. G.;Rogers, J. A.; Lewis, J. A. Science 2009, 323,1590-1593.

[210]“X-ray Absorption Spectroscopy Studies of Model Catalysts,” Small, M.;Sanchez,S.; Nuzzo, R. G.; Frenkel, A. I. Synch.Rad. News 2009, 22, 6-11.

[209]“Structural Characterization ofBimetallic Nanomaterials with Overlapping X-ray Absorption Edges,”Menard, L. D.; Wang, Q.; Kang,J. H.; Sealey, A. J.; Girolami, G. S.; Teng, X.; Frenkel, A. I.; Nuzzo,R. G. Phys. Rev. B. 2009,80,064111/1-11.

[208]“TheEmergenceof Non-Bulk Properties inSupported Metal Clusters: Negative Thermal Expansion and AtomicDisorder in PtNanoclusters Supported on γ-Al2O3,”Sanchez, S.I.; Menard, L. D.; Bram, A.; Kang, J. H.; Small, M. W.; Frenkel A. I.;Nuzzo,R. G. J. Am. Chem. Soc. 2009,131, 7040-7054.

[207]“Nanoenergetic Materials: Boron Nanoparticles from the Pyrolysis ofDecaboraneand their Functionalization,” Noh, W.; Nuzzo, R. G.; Girolami, G. S. Chem. Comm. 2009,22,3214-3215.

[206] “Visualizing the Effect ofMicroenvironmenton the Spatiotemporal RhoA and Src Activities in Live Cells by FRET,”Kim, T.–J.; Xu, J.; Dong, R.; Wheeler, B. C.; Nuzzo, R. G.; Wang, Y. Small 2009,5,1453-1459.

[203]“Textural Guidance Cues for Controlling Process Outgrowth of MammalianNeurons,” Hanson, J. N.; Mitchell, J.; Heien, M. L.; Motala, M. A.;Sweedler,J. V.; Gillette, M. A.; Nuzzo, R. G. Labon a Chip 2009, 9, 122-131.

style="position:absolute; top: 45%; left: 0pt;"[202]“Soft Lithography for Microfluidic Microelectromechanical Systems(MEMS) andOptical Devices,” Mitrovski, S. M.; Avasthy, S.; Erickson, E. M.;Stewart, M.E.; Rogers, J. A.; Nuzzo, R. G. in “UnconventionalNanopatterning Techniques and Applications,” Rogers, J. A.;.Lee,H. H. Eds.:Wiley (NJ), 2009, 295-324.


[205]“Ultrathin Silicon Solar Microcells forSemitransparent, Mechanically Flexible and Microconcentrator ModuleDesigns,” Yoon,J; Baca, A. J.; Park, S.-I.; Elvikis, P.; Geddes, J. B.; Li, L.; Kim,R. H.;Xiao, J.; Wang, S.; Kim, T. H.; Motala, M. J.; Ahn, B. Y.; Duoss, E.;Lewis, J.A.; Nuzzo, R. G.; Ferreira, P. M.; Huang,Y. Y.; Rockett, A.; Rogers; J.A. Nature Materials 2008,7,907-915.

[204]“Seeing Molecules by Eye: Surface Plasmon Resonance Imaging at VisibleWavelengths with High Spatial Resolution and Sub-MonolayerSensitivity,” Yao,J.; Stewart, M. E.; Maria, J.; Gray, S. K.; Rogers, J. A.; Nuzzo, R. G.Angewandte Chemie Intl. Ed. 2008, 47,5013-5017.

[201]“Complementary Logic Gates and Ring Oscillators on Plastic Substratesby Use ofPrinted Ribbons of Single-Crystalline Silicon,” Kim, D.-H.; Ahn, J.-H.;Kim,H.-S.; Lee, K. J.; Kim, T.-H.; Yu, C.-J.; Nuzzo, R. G.; Rogers, J. A. IEEE Electron. Dev. Lett. 2008,29(1),73-76.

style="position:absolute; top: 45%; left: 0pt;"[200]“Nanostructured Plasmonic Sensors,” Stewart, M. N.; Anderton, C. R.;Yao, J.;Thompson, L. B.; Maria, J.; Gray, S. K.; Rogers, J. A; Nuzzo, R. G. Chem. Rev. 2008,108,494-521.

[199]“Dynamic Structure in Supported Pt Nanoclusters: Real-time DensityFunctionalTheory and X-ray Spectroscopy Simulations” Villa, F.; Rehr, J. J.; Kas,J.;Nuzzo, R. G.; Frenkel, A. I. Phys. Rev. BCondensed Matter and Materials Physics Rapid Comm. 2008, 78,121404/1-4.

[195]“Coordination-Dependent Surface Atomic Contraction in Nanocrystals,”Huang, W.J.; Sun, R.; Tao, J.; Menard, L. D.; Nuzzo, R. G.; Zuo, J. M. Nature Materials 2008,7,308-314.


[198]“Competing Fracture in Kinetically Controlled Transfer Printing,” Feng,X.;Meitl, M. A.; Bowen, A.; Huang, Y.; Nuzzo, R. G.; Rogers, J. A. Langmuir 2007,25,12555-12560.

[197]“A Microfluidic Device for the Discrimination of Single NucleotidePolymorphisms in DNA Oligomers Using Electrochemically ActuatedAlkalineDehybridization,” Zhang, H.;Mitrovski, S. M.; Nuzzo, R. G. Analyt. Chem. 2007, 79, 9014-9021.

[196] “Mass SpectrometricImaging of PeptideRelease from neuronal Cells within Microfluidic Devices,” Jo, K.;Heien, M. L.;Thompson, L. B.; Zhong, M.; Nuzzo, R. G.; Sweedler, J. V. Labon a Chip 2007, 7, 1454-1460.

[194]“TangentialLigand-Induced Strain inIcosohedral Au13,” Guilamov, O.; Frenkel,A. I.; Menard, L. D.; Nuzzo, R. G.; Kronik, L. J.Am.Chem. Soc. 2007, 129, 10978-10979.

[192]“Microfluidic Devices for Culturing Primary Mammalian Neurons at LowDensities,” Millet, L. J.; Stewart, M. E.; Sweedler, J. V.; Nuzzo, R.G.;Gillette, M. A. Lab on a Chip 2007, 7,987-994.

[191]“Bendable Integrated Circuits onPlastic Substrates by Use of Printed Ribbons of Single-CrystallineSilicon,”Ahn, J.-H.; Kim, H.-S.; Menard, E.; Lee, K. J.; Zhua, Z.; Kim, D. H.;Nuzzo, R.G.; Rogers, J. A.; Amlani, I.; Thomas, S. G. Appl.Phys.Lett. 2007, 90,213501/1-3.

[190]“The Adsorption of Linear Alkanes on Cu(111): Temperature and ChainLengthDependence of the Softened Vibrational Mode,” Fosser, K. A.; Kang, J.H.;Nuzzo, R. G.; Wőll, Ch. J. Chem. Phys.2007, 126,194707/1-10.

[189]“Optical Transduction of Chemical Forces,” Mack, N. H.; Wackerly, J.W.;Malyarchuk, V.; Stewart, M.; Rogers, J. A.; Moore, J. S.; Nuzzo, R. G. Nano Letters 2007,7,733-737.

[188]“Spatially Resolved Biosensing With a Molded Plasmonic Crystal,”Malyarchuk,V.; Stewart, M.; Nuzzo, R. G.; Rogers, J. A. Appl.Phys. Lett. 2007,90,203113/1-3.

[184]“Variably Elastic Hydrogels Patterned via Capillary Action in MicroChannels,”Dong, R.; Jensen, T. W.; Leckband, D. E.; Nuzzo, R. G. Langmuir2007, 23,1483-1488.


[193]“Unconventional Methods for Forming Nanopatterns,” Motala, M. A.,Stewart, M.N.; Yao, J.; Thompson, L.; Nuzzo, R. G. (an invited review) Journalof Nanoengineering and Nanosystems 2006(2007), 220, 81-138.

[187]“HeterogeneouslyIntegrated,Three Dimensional Electronics by Use of Printed SemiconductorNanomaterials,”Ahn, J-H.; Kim, H-S.; Lee, K. J.; Jeon, S.; Kang, S. J.; Sun, Y.;Nuzzo, R. G.;Rogers, J. A. Science 2006, 314,1754-1757.

[186]“Quantitative Multispectral Biosensing and 1-D Imaging Using Quasi-3DPlasmonicCrystals,” Stewart, M. E.;. Mack, N. H.; Malyarchuk, V.; Soares, J. A.N. T.;Lee, T.-W.; Gray, S. K.; Nuzzo, R. G.; Rogers, J. A. Proc.Nat. Acad. Sci. 2006, 103, 17143-17148.

[185]“Preparation of TiO2-Supported Au NanoparticleCatalystsfrom a Au13Cluster Precursor: Ligand Removal Using Ozone Exposure versus a RapidThermalTreatment,” Xu. F.; Menard, L. D.; Nuzzo, R. G.; Yang, J. C. J. Catal. 2006,243,64-73.

[183]“UnusualNon-Bulk Propertiesin Nanoscale Materials: Thermal Metal-Metal Bond Contraction ofγ-Alumina-Supported Pt Catalysts,” Kang,J. H.;Menard, L.D.; Nuzzo, R. G.; Frenkel, A. I. J.Amer Chem. Soc. 2006, 128,12068-12069.

[182]"Micron andSubmicronPatterning of Polydimethylsiloxane Resists on Electronic Materials byDecalTransfer Lithography and Reactive Ion-Beam Etching: Application to theFabrication of High-Mobility, Thin-Film Transistors” Ahn, H.;Lee, K. J.; Childs, W. R.; Rogers, J. A.; Nuzzo, R. G.; Shim,A. J. Appl. Phys. 2006,100,084907/1-084907/7.

[181]“HighSpeed,MechanicallyFlexible Single Crystal Silicon Thin Film Transistors on PlasticSubstrates,”Ahn, J.-H.; Kim, H.-S.; Lee, K. J.; Zhu, Z.; Menard, E.; Nuzzo, R. G.;Rogers IEEE Electron. Dev. Lett. 2006, 27(6),460-462.

[180]“Bendable GaN High Electron Mobility Transistors on PlasticSubstrates,” Lee,K. J.; Meitl, M. A.; Kumar, V.; Adesida, I.;Rogers, J. A.;Nuzzo, R. G. J. Appl.Phys. 2006, 100, 124507/1-124507/4.

[179]“Sub-NanometerAu MonolayerProtected Clusters Exhibiting Molecule-like Electronic Behavior:QuantitativeHAADF-STEM and Electrochemical Characterization of Clusters withPrecise AtomicStoichiometry,” Menard, L. D.; Gao, S.; Xu, H.; Twesten, R. D.; Harper,A. S.;Song, Y.; Wang, G.; Douglas, A. D.; Yang, J. C.; Frenkel, A. I.; Nuzzo,R. G.;Murray, R. W. J. Phys. Chem. B 2006, 110,12874-12883.

[178]“StructuralDynamics ofUltra-small Monolayer Protected Clusters: Metal Core Bonding Motifs ofMonodispersed Icosahedral Au13 and Larger AuNanoparticlesasRevealed by X-Ray Adsorption Spectroscopy and Transmission ElectronMicroscopy,” Menard, L. D.; Xu, H.; Gao, S.; Twesten, R. D.; Harper, A.S.; Song,Y.; Wang, G.; Douglas, A. D.; Yang, J. C.; Frenkel, A. I.; Murray, R. W.; Nuzzo, R. G. J.Phys. Chem. B 2006, 110,14564-14573.

[177]“Quantitative Imaging of Protein Adsorption on Patterned Organic ThinFilmArrays using Secondary Electron Emission,” Mack, N. H.; Dong, R.;Nuzzo, R. G. J. Amer. Chem. Soc. 2006, 128,7871-7881.

[176]“Effects ofTemperature on theAlignment and Electro-optical Responses of Nanoscale Nematic LiquidCrystallineFilms,” Lee, L.-M., Kwon, H. J.; Nuzzo, R. G.; Schweizer, K. S. J. Phys. Chem. B 2006,110,15782-15790.

[175]“Anchoring and Electro-optical Dynamics of Thin Liquid CrystallineFilms in aPolyimide Cell:  Experimentand Theory,”Lee, L. M.; Kwon, H. J.; Kang, J. H.; Nuzzo, R. G.; Schweizer, K. S. J. Chem. Phys. 2006,125,024705(1-16).

[174]“A Passive Microfluidic Hydrogen-Air Fuel Cell with ExceptionalStability andHigh Performance,” Mitrovski, S. M.; Nuzzo, R. G. Labon aChip 2006¸6,353-361.

[172]“Transfer Printing By Kinetic Control Of Adhesion To A Soft,ElastomericStamp,” Meitl, M. A.; Zhu, Z.; Kumar, V.; Lee,K. J.; Feng,X;  Huang,Y. Y.; Adesida, I.;Nuzzo, R.G.; Rogers, J. A. Nature Materials 2006, 5,33-38.

[171]“Origin of Bulk-like Structure and Bond Distributions of Pt37and Pt6Ru31Clusters on Carbon,” Wang, L.-L; Khare, S. V.; Chirita, V.; Johnson, D.D.;Rockett, A. A.; Frenkel, A. I.; Mack, N. H.; Nuzzo, R. G. J.Amer. Chem. Soc. 2006, 128, 131-142.


[173]“Additive Soft Lithographic Patterning of Submicron and Nanometer-ScaleLargeArea Resists on Electronic Materials,” Ahn, H.; Lee, K. J.; Shim, A.;Rogers,J. A.; Nuzzo, R. G. Nano Letters 2005, 5,2533-2537.

[170]“A High Performance Plasmonic Crystal Chemical Sensor,” Malyarchuk, V.;Hua,F.; Mack, N. H.; White, J. O.; Nuzzo, R. G.; Rogers, J. A. OpticsExpress 2005, 13, 5669-5675.

[169]“Recent Progress in Soft Lithography,” Rogers, J. A.; Nuzzo, R. G. Materials Today, 2005,8,50-56.

[168]“Large Area, Selective Transfer of Microstructured Silicon (µs-Si): APrinting-based Approach to High Performance Thin Film TransistorsSupported onFlexible Substrates,” Lee, K. J.; Motala, M. J.; Meitl, M. A.; Childs,W. R.;Menard, E.; Shim, A. K.; Rogers, J. A.; Nuzzo, R. G. Adv.Mater. 2005, 17, 2332-2336.

[167]“A Printable Form of Single Crystal Gallium Nitride for FlexibleOptoelectronicSystems," Lee, K. J.; Lee, J.; Hwang, H.; Reitmeier, Z. J.; Davis, R.F.;Rogers J. A.; Nuzzo,R. G. Small 2005, 1,1164-1168.

[166]“Spin on Dopants for High Performance Single Crystal SiliconTransistors onFlexible Plastic Substrates,” Zhu,Z.-T., Menard, E.; Hurley, K.; Nuzzo, R. G.; Rogers, J.A. Appl. Phys. Lett. 2005,86,133507/1-133507/3.

[165]“Bendable Single Crystal Silicon Thin Film Transistors Formed byPrinting onPlastic Substrates,” Menard, E.; Nuzzo, R. G.; Rogers, J. A. Appl. Phys. Lett., 2005,86,093507/1-093507/3.

[164]“An Electrochemically Driven Poly(dimethylsiloxane) MicrofluidicActuator:Oxygen Sensing and Programmable Flows and pH Gradients,” Mitrovski, S.M.;Nuzzo, R. G. Lab on a Chip,2005, 5, 634-645.

[163]“Masterless Soft Lithography: PatterningUVO-Induced Adhesion on Poly(dimethylsiloxane) Surfaces,”Childs, W. R.;Motala, M. J.; Lee, K. J.; Nuzzo, R. G. Langmuir,2005, 21,10096-10105.

[162]“Photolithographic Route to The Fabrication of Micro/Nanowires of III-VSemiconductors,” Sun, Y.; Khang, D.-Y;Hua, F.; Hurley, K.; Nuzzo, R. G.; Rogers, J. A. Adv. Funct.Mater. 2005, 15,30-40.

[161]“Large-Area Patterning of Coinage Metal Thin Films Using Decal TransferLithography,” Childs, W. R.; Nuzzo, R. G. Langmuir2005, 21,195-202.

[160]“Near-IR Luminescence of Monolayer-Protected Metal Clusters,” Wang, G.;Huang, T.;Murray, R. W.; Menard, L.;Nuzzo, R. G. J. Amer. Chem. Soc. 2005, 127,812-813.

[158]“Fabrication of Stable Metallic Patterns Embedded inPoly(dimethylsiloxane):Patterning Applications in Non-Planar Electronic and Lab-on-a-chipDevices,”Lee, K. J.; Fosser, K. A.; Nuzzo, R. G. Adv.Funct. Mat. 2005, 15, 557-566.

[157]“Self-Assembled Monolayers of Thiolates on Metals as a Form ofNanotechnology,”Love, J. C.; Estroff, L. A.; Kriebel, J. K.; Nuzzo, R. G.; Whitesides,G. M. Chem. Rev. 2005,105,1103-1169.


[159]“Patterning of Thin-Film Microstructures on Non-Planar SubstrateSurfaces UsingDecal Transfer Lithography,” Childs, W. R.; Nuzzo, R. G. Adv.Mater. 2004, 16, 1323-1327.

[156]“A Printable Form of Silicon for High Performance Thin FilmTransistors,”Menard, E.; Lee, K.; Khang, D.-Y.; Nuzzo, R. G.; Rogers, J. A. Appl. Phys. Lett. 2004.84,5398-5400.

[155]“MicrofluidicDevicesfor Energy Conversion: PlanarIntegration and Performance of a Passive, Fully Immersed H2-O2 FuelCell,”Mitrovski, S. M.; Elliott, L. C. C.; Nuzzo, R. G. Langmuir2004, 20,6974-6976.

[154]“Growth Kinetics and Morphology of Self-Assembled Monolayers formed byContactPrinting 7-octenyltrichlorosilane and Octadecyltrichlorosilane onSi(100)Wafers,” Harada, Y; Girolami, G. S.; Nuzzo, R.G. Langmuir 2004,20,10878-10888.

[153]“EngineeringtheMorphologyand Electrophysiological Parameters of Cultured Neurons by MicrofluidicSurfacePatterning,”Romanova, E. V.; Fosser, K. A.; Rubakhin, S. S.; Nuzzo,R. G.; Sweedler, J. V. FASEB JournalExpress 2004, 18(11), 1267-1269(ePub 2004 June 18).

[151]“Electrosynthesis of ReS4. XAS Analysis of ReS2,Re2S7,and ReS4,” Schwarz, D. E.; Frenkel, A. I.;Nuzzo, R. G.;Rauchfuss,T. B.; Vairavamurthy, A.Chem.Mater. 2004, 16, 151-158.

[150]“Phase-Dependent Electrochemical Properties of PolarSelf-Assembled Monolayers Modified via the Fusion of Mixed PhospholipidVesicles,” Twardowski, M.; Nuzzo, R. G. Langmuir2004, 20,175-180.

[149]“Soft-lithographic Fabrication of an Image Sensor Array on a CurvedSubstrate,”Jin, H. –C.; Abelson, J. R.; Erhardt, M. K.; Nuzzo, R. G. J.Vac Sci. Technol. B. 2004,22, 2548-2551.


[152]“Macromolecules at Surfaces: ResearchChallenges and Opportunities from Tribology to Biology,”Granick, S.;Kumar, S. K.; Amis, E. J.; Antonietti, M.; Balazs, A. C.; Chakraborty,A. K.;Grest, G. S.; Hawker, C.; Janmey, P.; Kramer, E. J.; Nuzzo, R. G.;Russell, T.P.; Safinya, C. R. J. Pol. Sci. B:Polymer Physics 2003, 41,2755-2793

[148]“Fabricationof Patterned Multicomponent Protein Gradients and GradientArrays using Microfluidic Depletion,” Fosser, K. A.;Nuzzo, R.G. Analyt. Chem. 2003,75,5775-5782.

[147]MolecularRecognition at Model OrganicInterfaces: Electrochemical Discrimination Using Self-AssembledMonolayers(SAMs) Modified via the Fusion of Phospholipid Vesicles,”Twardowski,M.; Nuzzo, R. G. Langmuir,” 2003, 19,9781-9791.

[145]“Catalytic Amplification of Patterning via Surface-ConfinedRing-OpeningMetathesis Polymerization on Mixed Primer Layers Formed by ContactPrinting,”Harada, Y.; Girolami, G. S.; Nuzzo, R. G. Langmuir 2003, 19,5104-5114.

[144]“TheSize-Dependent StructuralPhase Behaviors of Supported Bimetallic (Pt-Ru) Nanoparticles,” Hills,C. W.;Mack, N.; Nuzzo, R. G. J. Phys. Chem. B. 2003, 107,2626-2636.

[141]“Formation andStructure ofSelf-Assembled Monolayers of Alkanethiolates on Palladium,” Love, J.C.; Wolfe,D. B.; Haasch, R. T.; Paul, K. E.; Chabinyc, M. L.; Whitesides, G. M.;Nuzzo,R. G. J. Am Chem. Soc. 2003,125,2597-2609.

[140]“The Origin of Soft Vibrational Modes of Alkanes Adsorbed on Cu: AnExperimental and Theoretical Investigation,” Fosser, K. A.; Nuzzo, R.G.;Bagus, P. S.; Wőll, Ch. J. Chem. Phys. 2003, 118, 5115-5131.


[146]“Future directions in solidstatechemistry:reportof the NSF-sponsored workshop” Cava,R. J.;DiSalvo, F. J.; Brus, L. E.; Dunbar, K. R.; Gorman, C. B.; Haile, S.M.;Interrante, L. V.; Musfeldt, J. L.; Navrotsky, A.; Nuzzo, R. G.;Pickett, W.E.; Wilkinson, A. P.; Ahn, C.; Allen, J. W.; Burns, P. C.; Ceder, G.;Chidsey,C. E. D.; Clegg, W.; Coronado, E.; Dai, H.; Deem, M. W.; Dunn, B. S.;Galli,G.; Jacobson, A. J.; Kanatzidis, M.; Lin, W.; Manthiram, A.; Mrksich,M.;Norris, D.; Nozik, A. J.; Peng, X.; Rawn, C.; Rolison, D.; Singh, D.J.; Toby,B. H.; Tolbert, S.; Wiesner, U. B.; Woodward, P. M.; Yang, P. Progress in Solid State Chemistry 2002, 30,1-101.

[143]“Effects ofSurface Morphologyon the Anchoring and Electro-optical Dynamics of Confined NanoscaleLiquidCrystalline Films,” Noble, A. R.; Kwon, H. J.; Nuzzo, R. G. J.Am.Chem.Soc. 2002, 124;15020-15029.

[142]“DecalTransferMicrolithography. A New Soft-Lithographic Patterning Method,” Childs,W. R.;Nuzzo, R. G. J. Am Chem. Soc. 2002,124,13583-13596.

[138]“ChemicallyMediated GrainGrowth in Nanotextured Au and Au/Cu Alloy Thin Films: Novel Substratesfor theFormation of Self-Assembled Monolayers,” Twardowski, M.; Nuzzo, R. G. Langmuir2002, 18, 5529-5538.

[137]“ASplitMicrochannel Designand Model to Compensate for Electroosmotic Flow Instabilities inMicroseparations,” Monahan, J.; Fosser, K. A.; Gewirth, A. A.; Nuzzo,R. G. Labon a Chip 2002, 2,81-87.

[136]“TheAdsorptionofCyclopropane and Cyclohexane on Cu(111): An Experimental andTheoreticalInvestigation of the Nature of the Metal C-H Interaction,” Fosser, K.A.;Nuzzo, R. G.; Bagus, P. S.; Wőll, Ch. Angewandte Chemie.2002, 41, 1735-1737.

[126]“IndirectFluorescence Detection of Simple Sugars via High-pH Electrophoresis inPoly(dimethylsiloxane) Microfluidic Chips,” Monahan,J.;Gewirth, A.A.; Nuzzo, R. G. Electrophoresis 2002, 23,2347-2354.


[135]“A View from the Inside: Complexity in the Atomic Scale Ordering ofMetalNanoparticles,” Frenkel, A. I.; Hills, C.W.; Nuzzo, R. G. (an invitedfeaturearticle) J. Phys. Chem. B. 2001,105,12689-12703.

[134]“The Future of Electronics Manufacturing is Revealed in the FinePrint,” Nuzzo,R. G. Proc. Nat. Acad. Sci., 2001,98,4827-4829.

[133]“Driven Pattern Formation in Organic Thin Film Materials. ComplexOrganizationsin Microcontact Printing on Silicon via the Spontaneous Dewetting of aFunctionalized Perfluoropolyether Ink” Erhardt, M. K.; Nuzzo, R. G. J.PhysChem. B. 2001, 105,8776-8784.

[132]“The Assembly and Characterization of SAMs Formed by the Adsorption ofAlkanethiols on Zinc Selenide Substrates,” Luginbuhl, A. R.; Nuzzo, R.G. Langmuir 2001, 17,3937-3944.

[131]“A Method for Filling Complex Polymeric Microfluidic Devices andArrays,”Monahan, J.; Gewirth, A. A.; Nuzzo, R. G. Analyt.Chem. 2001, 73,3193-3197.

[130]“Catalytic Amplification of the Soft Lithographic Patterning of Si.Non-Electrochemical Orthogonal Fabrication of Photoluminescent PorousSi PixelArrays,” Harada, Y.; Li, X.; Bohn, P. W.; Nuzzo, R. G. J. AmChem.Soc. 2001, 123,8709-8717.

[129]“Kinetic and Mechanistic Studies of the Chemical Vapor Deposition ofTungstenNitride from bis(tertbutylimido)bis(tertbutylamido)tungsten,” Crane, E.L.;Chiu, H. –T..; Nuzzo, R. G. J. Phys.Chem. B. 2001, 105,3549-3556.

[128]“The Phase-Behavior of Multicomponent SAMs Directs the NanoscaleTexturing ofSi(100) by Wet Etching,” Finnie, K. R.; Nuzzo, R. G. Langmuir2001, 17, 1250-1254.


[127]“Low-TemperatureFabrication of Si Thin Film Transistor Microstructuresby SoftLithographic Patterning on Curved and Planar Surfaces,” Erhardt,M. K.;Jin, H. –C.; Abelson, J. R.;Nuzzo, R. G. Chem. Mater. 2000, 12, 3306-3315.

[126]“Hybrid PDMS Microchips for Use in High pH Electrophoretic Separations:Separation and Indirect Detection of Simple Sugars,” Monahan, J.;Gewirth, A. A.; Nuzzo, R. G. Electrophoresis 2002, 23, 2347-2354.

[125]“Collision-Induced Desorption and Reaction on Hydrogen-Covered Al(111)Single Crystals—Hydrogen in Aluminum?” Crane, E. L.; Nuzzo, R. G. J.Phys. Chem. B. 2001, 105, 3052-3061.

[124]“Formation and Patterning of Self-Assembled Monolayers Derived fromLong-ChainOrganosilicon Amphiphiles and Their Use as Templates in MaterialsMicrofabrication,” Finnie, K. R.; Nuzzo, R. G. Langmuir2000, 16, 6968-6976.

[123]“Additive Fabrication and the Mechanisms of Nucleation and Growth inChemicalVapor Deposition Processes,” Crane, E. L.; Girolami, G. S.; Nuzzo, R.G. Accounts of Chemical Research 2000,33, 869-877.

[122]“An Infrared Study of the Effects of Hydration on Cation-Loaded NafionThin Films,” Blanchard, R. M.;Nuzzo, R. G. J. Poly. Sci. Eng. B. 2000, 38,1512-1520.

[121]“Mechanistic Studies of CVD Metallization Processes: Reactions ofRhodium andPlatinum-Diketonate Complexes on Copper Surfaces,” Crane, E. L.; You,Y.; Lin, W.; Girolami; G. S.; Nuzzo, R G. J.Amer. Chem. Soc. 2000, 122, 3422-3435.

[120]“Fabrication of an Interdigitated Electrode Array Thin-Film Cell onZnSe andits Application to Electro-Optical Measurements,” Blanchard, R. M.;Luginbuhl,A. R.; Nuzzo, R. G. Analyt. Chem. 2000, 72,1365-1372.

[119]“Surface Effects on the Dynamics of Liquid Crystalline Thin FilmsConfined inNanoscale Cavities,” Luginbuhl, A. R.; Blanchard, R. M.; Nuzzo, R. G. J. Amer. Chem. Soc. 2000,122,3917-3926.

[118]“Structural Models and Desorption Energetics for Multilayer Assembliesof then-Alkanes on Pt(111),” Bishop, A. R.; Girolami, G. S.; Nuzzo, R. G. J. Phys. Chem. 2000,104,754-763.

[117]“Surface Mediated Segregation and Transport Processes in MixedHydrocarbonMultilayer Assemblies,” Bishop, A. R.; Girolami, G. S.; Nuzzo, R. G. J. Phys. Chem. 2000,104,747-753.

[115]“Surface Initiated Ring-Opening Metathesis Polymerization on Si/SiO2,”Kim, N. Y.; Jeon, N. L.; Choi, I. S.; Takami, S.; Harada, Y.; Finnie,K. R.,Girolami, G. S.; Nuzzo, R. G.; Whitesides, G. M.; Laibinis; P. E. Macromolecules, 2000,33,2793-2795.


[116]“Patterned Polymer Growth on Silicon Surfaces Using MicrocontactPrinting andSurface Initiated Polymerization,” Jeon, N. L.; Choi, I. S.; Kim, N.Y.;Harada, Y.; Finnie, K. R., Girolami, G. S.; Nuzzo, R. G.; Laibinis; P.E.; Whitesides,G. M. Appl. Phys. Lett. 1999, 75,4201-4203.

[113]“Fabrication of Pt-Si Schottky Diodes Using Soft-LithographicPatterning andSelective Chemical Vapor Deposition,” Erhardt, M. K.; Nuzzo, R G. Langmuir 1999,15,2188-2193.

[112]“Carbon Support Effects on Bimetallic Pt-Ru Nanoparticles Formed fromMolecularPrecursors,” Hills, C. W.; Nashner, M. S.; Frenkel, A.; Shapley, J. R.;Nuzzo,R. G. Langmuir 1999,15,690-700.

[111]“Thermal Phase Evolution of Pt-Si Intermetallic Thin Films Prepared bytheActivated Adsorption of SiH4 on Pt(100) andComparison toKnownStructural Models,” Bondos, J. C.; Drummer, N. E.; Gewirth, A. A.;Nuzzo, R. G. J. Amer. Chem. Soc. 1999, 121,2498-2507.

[110]“Observation and Origin of a Unique Growth Texture During the CVDMediatedGrowth of Intermetallic Thin Films,” Bondos, J. C.; Gewirth, A. A.;Nuzzo, R.G. submitted to J. Amer. Chem. Soc..

[109]“The Morphological and Compositional Evolution of Pt-Si IntermetallicThinFilms Prepared by the Activated Adsorption of SiH4onPt(111),”Bondos, J. C.; Gewirth, A. A.; Nuzzo, R. G. J.Phys. Chem. 1999, 103, 3099-3109.

[102]“Structure and Reactivities of Cycloheptene, 1,3-Cycloheptadiene, andCycloheptatrieneon Pt(111),” Manner, W. L.; Hostetler, M. J.; Girolami, G. S.; Nuzzo,R. G. J. Phys. Chem. B1999, 103,6752-6763.


[114]“The Raft-like Structure of PtRu5,” Yang, J. C.;Bradley,S.;Nashner, M.; Nuzzo, R.; Gibson, J. M. Mater.Res. Soc. Proc. 1998, 497,109-113.

[113]“Fabrication of Pt-Si Schottky Diodes Using Soft-LithographicPatterning and Selective Chemical Vapor Deposition,” Erhardt, M. K.;Nuzzo, R G. Langmuir 1999, 15, 2188-2193. 1998,497,109-113.

[112]“Carbon Support Effects on Bimetallic Pt-Ru Nanoparticles Formed fromMolecular Precursors,” Hills, C. W.; Nashner, M. S.; Frenkel, A.;Shapley, J. R.; Nuzzo, R. G. Langmuir 1999, 15, 690-700. 1998,497,109-113.

[111]“Thermal Phase Evolution of Pt-Si Intermetallic Thin Films Prepared bythe Activated Adsorption of SiH4 on Pt(100) and Comparison to KnownStructural Models,” Bondos, J. C.; Drummer, N. E.; Gewirth, A. A.;Nuzzo, R. G. J. Amer. Chem. Soc. 1999, 121, 2498-2507. 1998,497,109-113.

[110]“Observation and Origin of a Unique Growth Texture During the CVDMediated Growth of Intermetallic Thin Films,” Bondos, J. C.; Gewirth,A. A.; Nuzzo, R. G. submitted to J. Amer. Chem. Soc. 1998,497,109-113.

[109]“The Morphological and Compositional Evolution of Pt-Si IntermetallicThin Films Prepared by the Activated Adsorption of SiH4 on Pt(111),”Bondos, J. C.; Gewirth, A. A.; Nuzzo, R. G. J. Phys. Chem. 1999, 103,3099-3109. 1998, 497,109-113.

[108]“Melting of Rod-like Molecules on Pt(111). Infrared SpectroscopicStudies ofIsotopically Labeled n-Alkanes,”Manner, W. L.; Bishop, A. R.; Girolami, G. S.; Nuzzo, R. G. J.Phys. Chem. 1998, 102, 8816-8824.

[107]“Semi-Permeable, Chemisorbed Adlayers of Focally-SubstitutedOrganothiolDendrons on Gold,” Gorman, C. B.; Miller, R. L.; Chen, K.; Bishop, A.R.;Haasch, R. T.; Nuzzo, R. G. Langmuir1998, 14,3312-3319.

[106]“Core Shell Inversion during Nucleation and Growth of Bimetallic Pt/RuNanoparticles,” Nashner, M. S.; Frenkel, A.; Sommerville, D. M.; Hills,C. W.;Shapley, J. R.; Nuzzo, R. G. J. Am. Chem.Soc. 1998, 120,8093-8101.

[105]“Fabrication of Si MOSFETs using Soft Lithography,” Jeon, N. L.; Hu,J.;Whitesides, G. W.; Erhardt, M. K.; Nuzzo, R. G. Adv.Mat. 1998, 10,1466-1469.

[104]“Carbon Supported Pt/Ru Catalysts Derived from OrganometallicPrecursors:Bimetallic Effects in the Catalytic Decomposition of Methanol,”Sommerville, D.M.; Nashner, M.S.; Lee, K.; Nuzzo, R.G.; Shapley, J.R. submitted to J. Chem. Phys.

[103]“Adsorption of Thiourea on Copper Electrodes Monitored by In-SituInfrared Spectroscopy,” Papanayiotou, D.; Nuzzo, R.G.;Alkire, R.C. J. Electrochem. Soc. 1998, 145,3366-3373.

[101]“Sequential Dehydrogenation of Cyclic C5 and C6 Hydrocarbons onPt(111),”Manner, W. L.; Girolami, G. S.; Nuzzo, R. G. J.Phys.Chem. B 1998, 102, 10295-10306.

[100]“Carbon Hydrogen Bond Activation and Cyclodehydrogenation Reactions ofCyclicC8 Hydrocarbons on Pt(111),” Manner, W. L.; Hostetler, M. J.; Dubois,L. H.;Girolami, G. S.; Nuzzo, R. G. J. Phys.Chem. 1998, 102, 2391-2402.

[99]“The C-H M Interaction and Reactivity Differences of n-Octane on the(1x1) and(5x20) Surfaces of Pt(100),” Manner, W. L.; Hostetler, M. J.; Girolami,G. S.;Nuzzo, R. G. Langmuir 1998, 14,1716-1724.

[98]“The Chemisorption Properties and Structural Evolution of Pt-SiIntermetallicThin Films Prepared by the Activated Adsorption of SiH4onPt(111),”Nashner, M. S.; Bondos, J. C.; Hostetler, M. J.; Gewirth, A. A.; Nuzzo,R. G. J. Phys. Chem. 1998,102, 6202-6211.

[97]“Transport Dynamics in Ordered Bilayer Assemblies of the n-Alkanes onPt(111),”Bishop, A. R.; Hostetler, M. J.; Girolami, G. S.; Nuzzo, R. G. J. Am. Chem. Soc. 1998,120,3305-3315.

[92]“Collision-induced Activation of Alkyl Fragments Derived from theDissociativeAdsorption of Isobutyl Iodide on Al(111),” Lohokare, S. P.; Crane, E.L.;Dubois, L. H.; Nuzzo, R. G. J. Chem.Phys. 1998, 108, 8640-8650.

[91]“Direct Organometallic Synthesis. The Metal Etching Reactions ofIsobutylIodide on Al(111),” Lohokare, S. P.; Crane, E. L.; Dubois, L. H.;Nuzzo, R. G. Langmuir 1998, 14,1328-1336.


[96]“Structural Characterization of Carbon Supported Ru-Pt Nanoparticlesderivedfrom the Molecular Precursor PtRu5C(CO)16,”Nashner, M.S.; Frenkel, A.; Adler, D.L.; Sommerville, D. M.; Shapley, J. R.;Nuzzo, R. G. J. Am. Chem. Soc. 1997, 119,7760-7771.

[95]“Selective Chemical Vapor Deposition of Platinum and Palladium DirectedbyMonolayers Patterned by Contact Printing,” Jeon, N. L.; Lin, W.;Erhardt, M.K.; Girolami, G. S.; Nuzzo, R. G. Langmuir1997, 13,3833-3838.

[94]“The Structure and Stability of Patterned Self-Assembled Films ofOctadecyltrichlorosilane Formed by Contact Printing,” Jeon, N. L.;Finnie, K.R.; Branshaw, K.; Nuzzo, R. G. Langmuir1997, 13,33-82-3391.

[93]“Additive Fabrication of Integrated Ferroelectric Thin Film CapacitorsUsingSelf-Assembled Thin-Film Templates,” Jeon, N. L.; Clem, P. G.; Lin, W.;Girolami, G. S.; Payne, D. A.; Nuzzo, R. G. Adv.Mat. 1997, 9,891-895.

[90]“Characterization and Catalytic Activity of Zeolite NaY Supported IrCatalysts,” Sommerville, D. M.; Nashner, M. S.; Nuzzo, R. G; Shapley,J. R. Catal. Lett. 1997,46,17-25.

[89]“Monolayer-mediated Deposition of Tantalum(V)oxide Thin Film StructuresfromSolution Precursors,” Clem, P. G.; Jeon, N. L.; Nuzzo, R. G.; Payne, D.A. J. Amer. Cer. Soc. 1997, 80,2821-2827.

[88]“Copper Deposition in the Presence of Surface Confined Additives,”Eliadis, E.D.; Nuzzo, R. G.; Gewirth, A. A.; Alkire, R. C. J.Electrochem. Soc. 1997, 144, 96-105.


[87]“Micron Scale Patterning of Solution Derived Ceramic Thin FilmsDirected bySelf-Assembled Monolayers” Clem, P. G.; Jeon, N. L.; Nuzzo, R. G.;Payne, D. A.  Mat.Res. Soc. Symp.Proc. 1996, 435, 521-526.

[86]“Bimetallic Catalyst Particle Nanostructure. Evolution from Molecular Cluster Precursors.,” Nashner, M.S.;Sommerville, D. M.; Lane, P. D.; Adler, D. L.; Shapley, J. R.; Nuzzo,R. G.J. Amer. Chem. Soc. 1996, 118,12964-12974.

[85]“A Monolayer-Based Lift-Off Process for Patterning CVD Copper ThinFilms,”Jeon, N. L.; Clem, P. G.; Payne, D. A.; Nuzzo, R. G. Langmuir1996, 12,5350-5355.

[84]“Observation ofUniaxialStructures of Underpotentially Deposited Cadmium on Au(111) with in-situ Scanning Tunneling Microscopy,”Bondos, J. C.; Gewirth, A. G.; Nuzzo, R. G. J.Phys. Chem. 1996, 100, 8617-8620.

[83]“Self-AssembledMonolayers:Recent Developments and Applications,” Bishop, A. R.; Nuzzo, R. G. Curr. Opin. Coll. Interface Sci. 1996, 1,127-136.

[82]“Synthesisofa Novel Volatile Platinum Complex for Use in CVD and a Study of theMechanismof its Thermal Decomposition in Solution,” Tagge, C.D.;Simpson, R. D.; Bergman. R.G.;Hostetler, M. J.; Girolami, G.S. ;  Nuzzo, R. G. J. Am. Chem.Soc.  1996,118,2634-2643.

[81]“MechanisticStudies ofPalladium Thin Film Growth from Palladium(II)ß-Diketonates. Part II.  Molecular Beam Studies andKinetic Analysisof the Transmetallation Reaction ofBis(hexafluoroacetylacetonato)palladium(II)on Copper Surfaces,” Lin, W.; Girolami, G. S.; Nuzzo, R. G. J.Am. Chem. Soc. 1996, 118,5988-5996.

[80]“MechanisticStudies ofPalladium Thin Film Growth from Palladium(II)ß-Diketonates. Part I.  Reactions ofBis(hexafluoroacetylacetonato)palladium(II) on Copper Surfaces,” Lin,W.;Weigand, B. C.; Nuzzo, R. G.; Girolami, G. S. J.Am. Chem.Soc. 1996, 118,5977-5987.


[79]"Patterning ofDielectricOxide Thin Layers by Microcontact Printing of Self-AssembledMonolayers,"Jeon, N. L.; Clem, P. G.; Nuzzo, R. G.; Payne, D. A. J.Mat. Res. 1995, 10, 2996-2999.

[78]"Determining theHybridization Differences for Amorphous Hydrogenated Carbon from theXPS C 1sEnvelope," Jackson, S. T.; Nuzzo, R. G. Appl.Surf. Sci. 1995, 90, 195-203.

[77]"TwoDimensionalMeltingTransitions of Rod-Like Molecules Analyzed by Reflection-AbsorptionInfraredSpectroscopy," Hostetler, M. J.; Manner, W. L.; Nuzzo, R. G.; Girolami,G.S. J. Phys. Chem. 1995,99,15269-15278.

[76]"TheUse ofPatternedSelf-Assembled Monolayers Formed by Microcontact Printing to DirectSelectiveMetallization by Chemical Vapor Deposition on Planar and Non-PlanarSubstrates," Jeon, N. L.; Nuzzo, R. G.; Xia, Y.; Mrksich, M.;Whitesides,G. M. Langmuir 1995,11,3024-3026.

[75]“Norbornadieneon Pt(111) is Not Bound as an h2,h2 Diene: Characterization of anUnexpectedh2,h1 Bonding Mode Involving an Agostic Pt···H-CInteraction,” Hostetler, M. J.;Nuzzo, R. G.; Girolami, G. S.; Dubois, L. H. Organometallics1995, 14,3377-3384.

[74]“Self-AssembledMonolayers(SAMs) of Alkanethiols with the Structure RNHCOCH2SH:Augmenting theStability of SAMsUsing Hydrogen Bonding,” Tam-Chang, S.-W.; Biebuyck, H. A.; Whitesides,G. M.;Jeon, N.; Nuzzo, R. G. Langmuir  1995,11, 4371-4382.

[73]“TheReactions ofDisilane onCu(111): Direct Observation of Competitive Dissociation,Disproportionation,and Island Thin-Film Growth Processes,” Lohokare, S.; Weigand, B. C.;Nuzzo, R.G. Langmuir 1995, 11, 3902-3912.

[72]“TheStructureand WettingProperties of w-Alkoxy-n-alkanethiolate Monolayers on Gold and Silver,”Laibinis, P. E.; Bain, C. D.; Nuzzo, R. G.; Whitesides, G. M. J. Phys. Chem. 1995,99,7663-7676.

[71]“Self-AssembledMonolayers ofLong-Chain Hydroxamic Acids on the Native Oxide of Metals,” Folkers, J.P.;Bucholz, S.; Laibinis, P. E.; Gorman, C. B.; Whitesides, G. M., Nuzzo,R. G. Langmuir 1995,11,813-824.

[70]“StructureReactivityCorrelations in the Reactions of Hydrocarbons on Transition MetalSurfaces. 2.Hydrogenation of the Bicyclic Alkenes Norbornene andBicyclo[2.2.2]octene on aPlatinum(111) Surface,” Hostetler, M. J.; Nuzzo, R. G.; Girolami, G. S.J. Am. Chem. Soc. 1995,117, 1814-1827.

[69]“Physical andSpectroscopicStudies of the Nucleation and Growth of Copper Thin Films on PolyimideSurfacesby Physical and Chemical Vapor Deposition,” Jeon, N. L.; Nuzzo, R. G. Langmuir 1995, 11,341-355.

[68]“ModelOrganicRearrangementson Aluminum Surfaces,” Dubois, L. H.; Bent, B. E.; Nuzzo, R. G. inSpringerSeries in Surface Sciences, Vol. 34,1994,Chapter 5, R. J. Madix Ed.

[67]“ReactionsofPrimary Organosilanes on Transition Metal Surfaces. Identification ofthe FirstSurface-Bound Silylynes,”Hostetler, M. J.; Nuzzo, R. G.; Girolami, G. S. J.Am.Chem. Soc. 1994, 116, 11608-11609.

[66]“StructureReactivityCorrelations in the Reactions of Hydrocarbons on Transition MetalSurfaces. 1.Ring Contraction of Cyclooctene, 1,3-Cyclooctadiene,1,5-Cyclooctadiene, andCyclooctatetraene to Benzene on a Platinum(111) Surface,” Hostetler, M.J.;Nuzzo, R. G.; Girolami, G. S.; Dubois, L. H. J.Phys. Chem. 1994, 98, 2952-2962.

[65]“TheImpact ofSurfaceProcessing on the Fabrication and Performance of Thin-Film, MultilayerSolarCollectors,” Nuzzo, R; Duke, C. B.; Chaffee, K.; Kassner, M.; Pitts, R.Crit. Rev. Surf. Chem. 1993, 3,67-80.

[64]“Si-HBondActivation on Cu:The Reaction of Silane on Cu(111),” Weigand, B. C.; Lohokare, S.;Nuzzo, R. G. J. Phys. Chem. 1993, 97,11553-11562.

[63]“SurfaceSelective Depositionof Palladium and Silver Films from Metal-Organic Precursors: A NovelRedoxTransmetallation Process” Lin, W.; Warren, T. H.; Nuzzo, R. G.;Girolami, G. S. J. Am. Chem. Soc. 1993, 115,11644-11645.

[62]“RingContractionofCyclooctene, 1,3-Cyclooctadiene, 1,5-Cyclooctadiene, andCyclooctatetraene toBenzene on Platinum(111) Surfaces,” Hostetler, M. J.; Dubois, L. H.;Nuzzo, R.G.; Girolami, G. S. .J. Am. Chem. Soc. 1993, 115,2044-2046.

[61]“TheMolecularOrdering ofOrganosulfur Compounds on Au(111) and Au(100): Adsorption from Solutionand inUltrahigh Vacuum,”  Dubois,L. H.;Zegarski, B. R.; Nuzzo, R. G. J. Chem.Phys. 1993, 98., 678-688.

[60]“TheSynthesis,Structure, andProperties of Model Organic Surfaces,” Dubois, L. H.; Nuzzo, R. G. Ann. Rev. Phys. Chem. 1992,43,437-463.

[59]“TheStructure ofMonolayersFormed by Coadsorption of Two n-Alkanethiols of Different Chain Lengthson Goldand Its Relation to Wetting,” Laibinis, P. E.; Whitesides, G. M.;Nuzzo, R. G. J. Phys. Chem. 1992, 96,5097-5105.

[58]“SurfaceReactions in theAluminum Catalyzed Direct Synthesis of Alkyl Silanes,” Bent, B. E.,Kao, C.-T.;Zegarski, B. R.; Dubois, L. H.; Nuzzo, R. G. J.Am. Chem.Soc. 1991, 113,9112- 9119.

[57]“Infrared Studiesof WaterAdsorption on Model Organic Surfaces,” Nuzzo, R. G.; Zegarski, B. R.;Korenic,E. M.; Dubois, L. H. J. Phys. Chem. 1992, 96,1355-1361.

[56]“TemperatureInducedReconstruction of Model Organic Surfaces,” Dubois, L. H.; Zegarski, B.R.;Nuzzo, R. G. J. Electron Spectrosc. Rel.Phen. 1990, 54/54, 1143-1148.

[55]“AComparison ofthe Structuresand Wetting Properties of Self-Assembled Monolayers of n-Alkanethiolson the Coinage Metal Surfaces, Cu, Ag, Au,”Laibinis; P. E.; Whitesides,G. M.; Allara, D. L.; Tao, Y.-T.; Parikh,A. N.;Nuzzo, R. G. J. Am. Chem. Soc. 1991, 113,7152-7167.

[54]“Metal-OrganicChemical VaporDeposition of Aluminum From Trialkylamine Alanes,” Gross, M. E.;Dubois, L. H.;Nuzzo, R. G.; Cheung, K. P. Proc. Mat.Res. Soc. 1991, 204, 383-390.

[53]“Aluminum ThinFilm Growth bythe Thermal Decomposition of Triethylamine Alane,” Dubois, L. H.;Zegarski, B.R.; Gross, M. E.; Nuzzo, R. G. Surf. Sci. 1991, 244,89-95.

[52]“Adsorption ofPoly(2-vinylpyridene)-Poly(styrene) Block Copolymers from TolueneSolutions,”Parsonage, E.; Tirrell, M.; Watanabe, H.; Nuzzo, R. G. Macromolecules1991, 24,1987-1995.

[51]“BandOffsetMeasurements forAlSb/ZnTe Heterojunctions,” Schwartz, G. P.; Gaultieri, G. J.; Feldman,R. D.;Austin, R. F.; Nuzzo, R. G. J. Vac. Sci.Technol. 1990. B(8), 747-750.

[50]“TheAdsorptionand ThermalDecomposition of Trimethylamine Alane on Aluminum and Silicon SingleCrystalSurfaces: Kinetic and Mechanistic Studies,” Kao, C.-T.; Dubois, L. H.;Zegarski, B. R.; Nuzzo, R. G. Surf. Sci. 1990, 236,77-84.

[49]“Chemical EtchingofSi(111)-(7x7) and Al/Si(111) by Atomic Hydrogen,” Kao, C.-T.; Dubois,L. H.;Nuzzo, R. G. J. Vac. Sci. Technol. 1991, A(9),228-231.

[48]“ThermalDecomposition of AlkylHalides on Aluminum: 2. The Formation and Thermal Decomposition ofSurfaceMetallacycles Derived from the Dissociative Chemisorption ofDihaloalkanes," Bent, B. E.; Nuzzo, R. G.; Zegarski, B. R.; Dubois, L.H. J. Am. Chem. Soc. 1991,113, 1143-1148.

[47]“ThermalDecomposition of AlkylHalides on Aluminum. 1. Carbon-Halogen Bond Cleavage and Surface-HydrideElimination Reactions,” Bent, B. E.; Nuzzo, R. G.; Zegarski, B. R.;Dubois, L.H. J. Am. Chem. Soc. 1991,113, 1137-1142. 

[46]“Studies of theTemperatureDependent Phase Behavior of Long Chain n-AlkylThiol Monolayers on Gold,” Nuzzo, R. G.; Korenic, E. M.; Dubois, L. H. J. Chem. Phys. 1990,93,767-773.

[45]“AluminumChemical VaporDeposition Using Triisobutylaluminum: Mechanism, Kinetics, andDeposition Ratesat Steady State,” Bent, B. E.; Dubois, L. H.; Nuzzo, R. G. Mat.Res. Soc. Proc. 1989, 131, 327-338.

[44]“FundamentalStudies ofMicroscopic Wetting on Organic Surfaces. 2. Interaction of SecondaryAdsorbateswith Chemically-Textured Organic Monolayers,” Dubois, L. H.; Zegarski,B. R.;Nuzzo, R. G. J. Am.Chem. Soc. 1990, 112, 570-579.

[43]“FundamentalStudies ofMicroscopic Wetting on Organic Surfaces. 1. Formation and StructuralCharacterization of a Self-Consistent Series of Polyfunctional OrganicMonolayers,” Nuzzo, R. G.; Dubois, L. H.; Allara, D. L. J.Am. Chem. Soc. 1990,112,558-569.

[42]“Formation ofMonolayer Filmsby the Spontaneous Assembly of Organic Thiols From Solution Onto Gold,”Bain,C.D.; Troughton, E.B.; Tao, Y.-T.; Evall, J.; Whitesides, G. M.; Nuzzo,R. G. J. Am.Chem. Soc. 1989, 111, 321-335.

[41]“CoreLevelPhotoemissionMeasurements of Heterojunction Valence Band Offsets in Highly StrainedSystems,” Schwartz, G. P.; Hybertsen, M.S.; Bevk, J.; Nuzzo, R. G.;Gualtieri,G. J.; Mannaerts, J.P. Phys. Rev. B 1989, 39,1235-1241.

[40]“SurfaceOrganometallicChemistry in the Chemical Vapor Deposition of Aluminum Films UsingTriisobutylaluminum: -Hydride and -AIkyl Elimination Reactions ofSurfaceAlkyl Intermediates,” Bent, B. E.; Nuzzo, R. G., Dubois, L. H. J Am.Chem. Soc. 1989, 111, 1634-1644.

[39]“ComplexReactions in theChemical Vapor Deposition of Aluminum by TriisobutylaluminumPyrolysis,” Bent,B. E.; Nuzzo, R. G.; Dubois, L. H. Mat.Res. Soc. Proc. 1988, 101,177-182.

[38]“Surface ChemicalReactions inthe MOCVD of Aluminum Films,” Bent, B. E.; Nuzzo, R. G.; Dubois, L. H. J. Vac.Sci. Technol. 1988, A6, 1920-1922.

[37]“FundamentalStudies of theInteractions of Adsorbates with Organic Surfaces,” Dubois, L. H.;Zegarski, B.R.; Nuzzo, R. G. Proc. Nat. Acad. Sci., 1987, 84,4739 4742.

[36]“Chemical Aspectsof ReactiveMetal and Energetic lon Interactions on Polyimide,” Nuzzo, R. G.; Wong,Y.-H.;Schwartz, G. P. Langmuir, 1987, 3,1136-1140.

[35]“Response toComment on X-rayPhotoemission Core Level Determination of the GaSb/AlSb HeterojunctionValence-Band Discontinuity,” Gualtieri, G. J.; Schwartz, G. P.; Nuzzo,R. G.;Sunder, W. A. Appl. Phys. Lett. 1987, 50, 1763-1764.

[34]“Valence BandDiscontinuitiesin (100) GaSb/AlSb and GaSb/InAs Heterojunctions,” Gualtieri, G. J.;Nuzzo, R.G.; Schwartz, G. P.; Malik, R. J.; Walker, J. F.; Feldman, L. C.;Sunder, W. A. J. Vac.Sci. Technol. B 1987, 5, 1284-1285.

[33]“Determination ofthe (100)InAs/GaSb Heterojunction Valence-Band Discontinuity by X-rayPhotoemission CoreLevel Spectroscopy,” Gualtieri, G. J.; Schwartz, G. P.; Nuzzo, R. G.;Malik, R.J.; Walker, J. F. J. Appl.Phys. 1987, 61, 5337-5341.

[32]“Monolayer FilmsPrepared bythe Spontaneous Self-Assembly of Symmetrical and Unsymmetrical DialkylSulfidesfrom Solution onto Gold Substrates: Structure, Properties, andReactivity ofConstituent Functional Groups,” Troughton, E. B.; Bain, C.; Whitesides,G. M.;Nuzzo, R. G.; Allara, D. L; Porter, M. D. Langmuir1988, 4,365-385.

[31]“TheChemisorption ofOrganosulfur Compounds on Gold Surfaces: Construction of Well-DefinedOrganicSolids,” Dubois, L. H.; Zegarski, B. R.; Nuzzo, R. G. J.Vac. Sci. Technol. A, 1987,5(4), 634-635.

[30]“Reconstructionof theInterface of Oxidatively Functionalized Polyethylene and Derivatives onHeating,”Holmes-Farley, S. R.; Reamey, R. H.; Nuzzo, R. G.; McCarthy, T. J.;Whitesides,G. M. Langmuir 1987, 3, 799-815.

[29]“X-RayPhotoemission Core LevelDetermination of the GaSb/AlSb Heterojunction Valence BandDiscontinuity,”Gualtieri, G. J.; Schwartz, G. P.; Nuzzo, R. G.; Sunder, W. A. Appl. Phys. Lett. 1986,49, 1037-1039.

[28]“FundamentalStudies of theChemisorption of Organosulfur Compounds on Au(111). Implications forMolecularSelf-Assembly on Gold Surfaces,” Nuzzo, R. G.; Zegarski, B. R.; Dubois,L. H. J. Am.Chem. Soc. 1987, 109, 733-740.

[27]“SpontaneouslyOrganizedMolecular Assemblies. 3. Preparation and Properties of SolutionAdsorbedMonolayers of Organic Disulfides on Gold Surfaces,” Nuzzo, R. G.;Fusco, F. A.;Allara, D. L. J. Am.Chem. Soc. 1987, 109, 2358-2368.

[26]“IntrinsicReactivity ofMagnesium Surfaces Toward Methyl Bromide,” Nuzzo, R. G.; Dubois, L. H. J. Am.Chem. Soc. 1986,108, 2881-2886.

[25]“SpontaneousOrganization ofCarboxylic Acid Monolayer Films in Ultrahigh Vacuum. KineticConstraints toAssembly via Gas Phase Adsorption,” Dubois, L. H.; Zegarski, B. R.;Nuzzo, R.G. Langmuir 1986, 2, 412-417.

[24]“IntermetallicCompounds asModels for Materials Formed at the Metal Crystallite-Oxide SupportInterface,”Nuzzo, R. G.; Dubois, L. H. A.C.S. Symp.Series 1986,298, 136-144.


[23]“TheInfluence ofCompositionalHeterogeneity on the Chemisorption and Reactivity of Small Moleculeson'Copper/Copper Silicide Surfaces,” Dubois, L. H.; Nuzzo, R. G. Langmuir 1985, 1, 663-669.

[22]“SpontaneouslyOrganizedMolecular Assemblies; 2. Quantitative Infrared SpectroscopicDetermination ofEquilibrium Structures of Solution Adsorbed n-AlkanoicAcids on an Oxidized Aluminum Surface,” Allara, D. L.; Nuzzo, R. G. Langmuir 1985, 1, 52-66.

[21]“SpontaneouslyOrganizedMolecular Assemblies; 1. Formation, Dynamics and Physical Properties ofn-Alkanoic Acids Adsorbed fromSolutionon an Oxidized Aluminum Surface,” Allara, D. L.; Nuzzo, R. G. Langmuir 1985,1, 45-52.

[20]“TheDecomposition of Silaneand Germane on Ni(l11): Implications for Heterogeneous Catalysis,”Dubois, L.H.; Nuzzo, R. G. Surf. Sci. 1985, 149, 133-145.

[19]“AnXPSStudy ofthe Reactionof Silane with Oxidized Copper, Silver, and Gold Surfaces,” Nuzzo, R.G.;Dubois, L. H. Surf. Sci. 1985, 149, 119-132.

[18]“TheChemisorption andCatalytic Properties of Nickel Intermetallic Compounds: Studies ofSingleCrystalline and High Surface Area, Supported Materials,” Nuzzo, R. G.;Dubois,L. H. Appl. Surf. Sci. 1984, 19, 407-413.

[17]“Reactivity ofIntermetallicThin Films Formed by the Surface Mediated Decomposition of Main GroupOrganometallic Compounds,” Dubois, L. H.; Nuzzo, R. G. J.Vac. Sci. Technol. 1984, A2, 441-445.

[16]“Aluminum FilmsPrepared byMetal-Organic Low Pressure Chemical Vapor Deposition,” Green, M. L.;Levy, R.A.; Nuzzo, R. G. Thin Solid Films 1984, 114, 367-377.

[15]“Derivatized,High SurfaceArea, Supported Nickel Catalysts,” Nuzzo, R. G.; Dubois, L. H.; Bowles,N. E.;Trecoske, M. A. J. Catal.1984, 85,267-271.

[14]“Preparation andCharacterization of Functionalized, Polyethylene Surfaces,” Nuzzo, R.G.;Smolinsky, G. Macromol. 1984, 17,1013-1019.

[13]“Adsorption ofBifunctionalOrganic Disulfides on Gold Surfaces,” Nuzzo, R. G.; Allara, D. L. J. Am.Chem. Soc. 1983, 105, 4481-4483.

[12]“AChemically-InducedEnhancement of Nucleation in Noble Metal Deposition,” Allara, D. L.;Nuzzo, R.G.; Hebard, A. F.; Padden, F. J.; Falcone, D. R. J.Vac. Sci. Technol. 1983,A1(2), 376-382.

[11]“SmallMoleculeChemisorptionon NiSi2:Implications for Heterogeneous Catalysis,” Dubois, L. H.; Nuzzo, R. G. J. Am.Chem. Soc. 1983,105, 365-369.

[10]“Synthesis of Functional Chelating Diphosphines Containing the Bis(2Diphenylphosphinoethyl)amino Moiety, and the Use of These Materials inthePreparation of Water-Soluble Diphosphine Complexes of TransitionMetals,”Nuzzo, R. G.; Haynie, S. L.; Wilson, M. E.; Whitesides, G. M. J. Org.Chem. 1981, 46, 2861-67.

[9]“ThermalDecomposition ofDi(cycloalkyl)bis(triethylphosphine)platinum (II) Complexes,” Nuzzo, R.G.;McCarthy, T. J.; Whitesides, G. M. J.Am. Chem. Soc. 1981,103, 3404-10.

[8]“Mechanisms ofThermalDecomposition of Diethylbis(triethylphosphine)platinum (II),” McCarthy,T. J.;Nuzzo, R. G.; Whitesides, G. M. J. Am.Chem. Soc. 1981, 103, 3396-403.

[7]“Preparation ofTertiaryPhosphine-Olefin Complexes of Platinum (0): A Convenient Synthesis ofEthylene-bis(triethylphosphine)platinum (0),” Nuzzo, R. G.; McCarthy,T. J.;Whitesides, G. M. Inorg. Chem. 1981, 103,1312-4.

[6]“ApparentFluxionality inDiethyl(triethylphosphine)-platinum (II), a Coordinatively UnsaturatedIntermediate in -Hydride Elimination,” McCarthy, T. J.; Nuzzo, R. G.;Whitesides, G. M. J. Am.Chem. Soc. 1981, 103, 1676-8.

[5]“Water-SolubleComplexes of TertiaryPhosphines and Rhodium (I) as Homogeneous Catalysts,” Nuzzo, R. G.;Feitler, D.J.; Whitesides, G. M. J. Am. Chem. Soc. 1979,101, 3683-5.

[4]“Bis(2-diphenylphosphinoethyl)amine. A Flexible Synthesis ofFunctionalizedChelating Diphosphines,” Wilson, M. E.; Nuzzo, R. G.; Whitesides, G. M.J. Am.Chem. Soc. 1978, 100, 2269-70.

[3]“SelectiveReduction ofSulfoxides,” Nuzzo, R. G.; Simon, H. J.; San Filippo, Jr., J, J. Org.Chem. 1977, 42, 568-9.

[2]“SubstituentEffects on theElectronic Nature of Carbon-Bonded Fluorine,” San Filippo, Jr., J.;Nuzzo, R.G.; Romano, L. J. J. Org.Chem. 1976, 41, 392-4.

[l]“Application of Lanthanide Shift Reagents to Alkyl Fluorides,” SanFilippo, Jr., J.; Nuzzo, R. G.; Romano, L. J. J. Am.Chem. Soc. 1975, 97, 2546.

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